stem/Quantum/Orbitals.md
2023-05-20 01:33:56 +01:00

648 B

\psi(r,\theta,\phi)=R(r)\cdot Y_{ml}(\theta, \phi)

Wave functions are products of Radial Function

  • $R_{n,l}(r)$ Spherical Harmonic
  • Y_{ml}(\theta, \phi)

Absolute value of wave function squared gives probability density of finding electron inside differential volume dV centred on r, \theta, \phi

|\psi(r,\theta,\phi)|^2

Quantum Numbers

n

Principal quantum number

  • 1, 2, 3...
  • Electron shell, electron energy and size of orbital
l

Orbital Angualar Momentum Number

  • 0-(n-1)
  • Shape of the orbital
    • 0 = s
    • 1 = p
    • 2 = d
m

Z-component / Magentic of l

  • -l to +l
  • Orientation of orbital