[Wave Function](Wave%20Function.md) ## Quantum Numbers $$n$$ Principal quantum number - 1, 2, 3... - ***Electron shell***, electron energy and size of orbital $$l$$ Orbital Angualar Momentum Number - $0-(n-1)$ - ***Shape*** of the orbital - 0 = s - 1 = p - 2 = d $$m$$ Z-component / Magentic of $l$ - $-l$ to $+l$ - ***Orientation*** of orbital ![wave-function-polar-segment](../img/wave-function-polar-segment.png) ## Filling 1. Aufbau - Start lowest in energy 2. Pauli's Exclusion - Max two electrons per orbital - No two electrons can have same n, l, m, s tuple 3. Hund's Rule of Maximum Multiplicity - Orbitals with same energy filled one at a time - Degenerate ![orbitals-radius](../img/orbitals-radius.png) ![wave-function-nodes](../img/wave-function-nodes.png) ## Radial ![radial-equations](../img/radial-equations.png) - Z = Atomic number - Bohr radius - $a_0=\frac \hbar {\alpha mc}$ - Normalisation - $\int_0^\infty r^2R_{nl}^*R_{nl}dr=1$ ![radius-electron-density-wf](../img/radius-electron-density-wf.png)