[[Wave Function]] ## Quantum Numbers $$n$$ Principal quantum number - 1, 2, 3... - ***Electron shell***, electron energy and size of orbital $$l$$ Orbital Angualar Momentum Number - $0-(n-1)$ - ***Shape*** of the orbital - 0 = s - 1 = p - 2 = d $$m$$ Z-component / Magentic of $l$ - $-l$ to $+l$ - ***Orientation*** of orbital ![[wave-function-polar-segment.png]] ## Filling 1. Aufbau - Start lowest in energy 2. Pauli's Exclusion - Max two electrons per orbital - No two electrons can have same n, l, m, s tuple 3. Hund's Rule of Maximum Multiplicity - Orbitals with same energy filled one at a time - Degenerate ![[orbitals-radius.png]] ![[wave-function-nodes.png]] ## Radial ![[radial-equations.png]] - Z = Atomic number - Bohr radius - $a_0=\frac \hbar {\alpha mc}$ - Normalisation - $\int_0^\infty r^2R_{nl}^*R_{nl}dr=1$ ![[radius-electron-density-wf.png]]